SBIR/STTR Research Award

THERE IS A NEED TO DEVELOP A PROCESS WHEREBY ORGANIC OCTANE ENHANCERS, CURRENTLY SYNTHESIZED FROM IMPORTED PETROCHEMICALS, MAY BE OBTAINED FROM A DOMESTIC RENEWABLE RESOURCE SUCH AS WOODY BIOMASS.

Award identifier 33cb591f8d29045aa1774060ca2b58ef1d9980eb735a1563cea0adf83c9f6f6bAwarding agency National Science Foundation

Award amount

$40,000

Program and phase

SBIR · Phase I

Award year

1985

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Award details

Awarding agency
National Science Foundation
Branch
Not reported
Recipient company
COVALENT ASSOC., INC.
Proposal award date
Not reported
Contract end date
Not reported
UEI
Not reported
Solicitation number
Not reported
Topic code
Not reported

Research abstract

THERE IS A NEED TO DEVELOP A PROCESS WHEREBY ORGANIC OCTANE ENHANCERS, CURRENTLY SYNTHESIZED FROM IMPORTED PETROCHEMICALS, MAY BE OBTAINED FROM A DOMESTIC RENEWABLE RESOURCE SUCH AS WOODY BIOMASS. PYROLYSIS OF LIGNOCELLULOSIC MATERIALS AT TEMPERATURES ABOVE 300 DEGREE CINVARIABLY LEADS TO LEVOGLUCOSAN AND A BEWILDERING VARIETY OF ALCOHOLS, KETONES, ACIDS, AND ALDEHYDES. WE HAVE DEMONSTRATED THAT LIGNOCELLULOSIC MATERIALS MAY BE SELECTIVELY PYROLYZED AT TEMPERATURES BELOW 250 DEGREE C TO SIMPLE ALIPHATIC KETONES AND PYRONES THROUGH THE AGENCY OF AN INORGANIC ADDITIVE. THESE ORGANIC COMPOUNDS HAVE RESEARCH OCTANE NUMBERS IN EXCESS OF 100, WHICH MAKES THEM SUITABLE FOR BOOSTING THE OCTANE NUMBER OF UNLEADED GASOLINE. WE PROPOSE TO ELABORATE UPON THESE FINDINGS BY STUDYING THE PYROLYSIS OF NON-COMMERCIAL HARDWOODS IN MOLTEN SALTS OVER THE TEMPERATURE RANGE OF 110 DEGREE TO 200 DEGREE C. WE WILL ALSO TEST THE FEASIBILITY OF ELECTROCHEMICALLY ASSISTING THE PYROLYTIC DEPOLYMERIZATION OF WOODY BIOMASS ATA SUITABLE WORKING ELECTRODE. THIS IS A TOTALLY NEW CONCEPTWHICH MAY RESULT IN ENHANCED YIELDS OF SELECTED COMPOUNDS ASWELL AS GIVE US A BETTER UNDERSTANDING OF THE OXIDATION STATES OF PYROLYTICALLY GENERATED REACTIVE INTERMEDIATES.

Technology keywords

Not reported

Agency intelligence

National Science Foundation

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